Synthesis, Structures, and Oxidation of Iridium(III) Alkyl Compounds Containing Thiolate and Dithiolate Ligands
β Scribed by Ka-Wang Chan; Yiu-Keung Sau; Qian-Feng Zhang; Wai-Yeung Wong; Ian D. Williams; Wa-Hung Leung
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 606 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
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## Abstract A series of cationic diiminoiridium(III) complexes [Ir(ppyβ__N__,__C__)~2~(Lβ__N__,__N__)](PF~6~) has been prepared [Hppy = 2βphenylpyridine; L = 4,4β²β__t__Bu~2~dpbpy (1), 4,4β²βMe~2~dpbpy (2), 4,4β²βMe~2~pbpy (3), 4,4β²βMe~2~bpy (4)] and their photophysical and electrochemical properties
A series of mixed cobalt(III) complexes [Co(pySe) 3 -n (N N) n ] n + [pySe= pyridine-2-selenolato (1 -); N N= 1,2-ethanediamine (en) and 2,2%-bipyridine (bpy); n= 0, 1 and 2] was prepared. The geometrical preference and trans influence of pySe are fairly different from those of pyridine-2-thiolate.