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Synthesis, structures, properties, and chemical-sensor application of iridium(III) bis-cyclometallated complexes with two pyridine-derived ligands

✍ Scribed by Wu-Sian Sie; Gene-Hsiang Lee; Kevin Yun-Da Tsai; I-Jy Chang; Kom-Bei Shiu


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
389 KB
Volume
890
Category
Article
ISSN
0022-2860

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## Abstract A series of cationic diiminoiridium(III) complexes [Ir(ppy‐__N__,__C__)~2~(L‐__N__,__N__)](PF~6~) has been prepared [Hppy = 2‐phenylpyridine; L = 4,4′‐__t__Bu~2~dpbpy (1), 4,4′‐Me~2~dpbpy (2), 4,4′‐Me~2~pbpy (3), 4,4′‐Me~2~bpy (4)] and their photophysical and electrochemical properties