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A Tris-Cyclometalated Iridium(III) Complex of 2-(5,5-Dioxido-dibenzothiophen-3-yl)pyridine: Synthesis, Structural, Redox and Photophysical Properties

โœ Scribed by Mustafa Tavasli; Sylvia Bettington; Igor F. Perepichka; Andrei S. Batsanov; Martin R. Bryce; Carsten Rothe; Andrew P. Monkman

Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
191 KB
Volume
2007
Category
Article
ISSN
1434-1948

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Synthesis, crystal structures and spectr
Synthesis, crystal structures and spectral properties of cobalt (II) complexes: [ Col (N3) ] ยท ClO4 and CoL (N3) 2 [L = tris( (3,5-dimethylpyrazol-1-yl) methyl)amine]
โœ Zhi-Hui Zhang; Hai-Long Yang; Zhi-Hong Ma; Ai-Di Qi ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 434 KB ๐Ÿ‘ 2 views

## Abstract Two monomeric cobalt(II) complexes, [CoL(N~3~)]ClO~4~ (1) and CoL(N~3~)~2~ (2), where L is tris((3,5โ€dimethylpyrazolโ€yl) methyl) amine, were synthesized and their crystal structures were determined by Xโ€ray diffraction technique. Complex 1 is five coordinated with one azide nitrogen ato