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Synthesis and structures of three edge-sharing bioctahedral compounds of (VI) a metals containing formamidinato ligands

✍ Scribed by F.Albert Cotton; David J. Maloney; Jianrui Su


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
736 KB
Volume
236
Category
Article
ISSN
0020-1693

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Electronic structure and metal-metal int
✍ F. Albert Cotton; Xuejun Feng πŸ“‚ Article πŸ“… 1996 πŸ› John Wiley and Sons 🌐 English βš– 884 KB

w Ab initio configuration interaction calculations have been performed for the title compounds to study the nature of the metal-metal interaction. By analyzing the energy diagrams and the CI wave functions, it can be shown that the metal-metal interaction in such compounds has a dual nature, namely,