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Synthesis, Structures, and Electronic Spectroscopy of Luminescent Acetylene- and (Buta-1,3-diyne)platinum Complexes

✍ Scribed by Ke Zhang; Jian Hu; Kwok Chu Chan; Kwok Yin Wong; John H. K. Yip


Publisher
John Wiley and Sons
Year
2007
Tongue
English
Weight
193 KB
Volume
2007
Category
Article
ISSN
1434-1948

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## Abstract The Ξ·^4^‐diphosphacyclobutadiene complexes [M(Ξ·^5^‐C~5~R~5~)(Ξ·^4^‐P~2~C~2~Bu)] (M ο£Ύ Co, Rh; R ο£Ύ H, Me), react with Rh(I), Pt(O), and Pt(II) centers via the phosphorus lone paris of the rings of afford mixed metal complexes. The crystal and molecular structure of the novel hexarhodium co