✦ LIBER ✦

Use of 1,3-diphosphacyclobutadiene complexes in the synthesis of mixed metal aggregates containing cobalt, rhodium, and platinum: Structure of a hexarhodium complex

✍ Scribed by Peter B. Hitchcock; Mohd Jamil Maah; John F. Nixon

Publisher: John Wiley and Sons
Year: 1991
Tongue: English
Weight: 775 KB
Volume: 2
Category: Article
ISSN: 1042-7163
DOI: 10.1002/hc.520020207

No coin nor oath required. For personal study only.

✦ Synopsis

Abstract

The η^4^‐diphosphacyclobutadiene complexes [M(η^5^‐C~5~R~5~)(η^4^‐P~2~C~2~Bu)] (M  Co, Rh; R  H, Me), react with Rh(I), Pt(O), and Pt(II) centers via the phosphorus lone paris of the rings of afford mixed metal complexes. The crystal and molecular structure of the novel hexarhodium complex [Rh~2~Cl~2~{Rh(P~2~C~2~Bu)}]~4~ (Cp  N^5^‐C~5~H~5~) is presented and discussed.

📜 SIMILAR VOLUMES

Complexes of Group 3 Metals and Lanthani

Complexes of Group 3 Metals and Lanthanides That Contain Siloxane-Bridged Bisaminopyridinato Ligands: Synthesis, Structure, and Application in the Ring-Opening Polymerization of Lactones

✍ Henrik Noss; Markus Oberthür; Christine Fischer; Winfried P. Kretschmer; Rhett K 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 272 KB 👁 2 views

The reaction of one equivalent of dilithiated O(SiMe 2 -Ap-H) 2 Cl(THF) Bu 4 N (5), O(SiMe 2 -Ap) 2 Y(BH 4 ) 2 Na(THF) 2 (6) and O(SiMe 2 -Ap) 2 Y(CH(TMS) 2 ) 2 Li(THF) 3 ( ), respectively. The [Ap-H = -N(2-amino-4-methylpyridine)] (1), generated in situ, with LnCl 3 (Ln = Y, Sm) in THF affords O(Si

Synthesis, Structure, and Redox Properti

Synthesis, Structure, and Redox Properties of a New Aqua Ruthenium Complex Containing the Tridentate [9]aneS3 and the Didentate 1,10-Phenanthroline Ligands

✍ Xavier Sala; Albert Poater; Isabel Romero; Montserrat Rodríguez; Antoni Llobet; 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 152 KB 👁 1 views

ChemInform Abstract: Solvothermal Synthe

ChemInform Abstract: Solvothermal Synthesis, Crystal Structure and Properties of [Mg(en)3][Sb4S7] — The First Thioantimonate(III) Containing a Main Group Metal Complex Cation as Structure Director.

✍ Enrique Quiroga-Gonzalez; Christian Naether; Wolfgang Bensch 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 2 views

Metal-Ion-Templated Polymers: Synthesis

Metal-Ion-Templated Polymers: Synthesis and Structure of N-(4-Vinylbenzyl)-1,4,7-Triazacyclononanezinc(II) Complexes, Their Copolymerization with Divinylbenzene, and Metal-Ion Selectivity Studies of the Demetalated Resins—Evidence for a Sandwich Complex in the Polymer Matrix

✍ Dr. Hong Chen; Dr. Marilyn M. Olmstead; Dr. Robert L. Albright; Dr. Jozsef Deven 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 535 KB

ChemInform Abstract: Transition-Metal Co

ChemInform Abstract: Transition-Metal Complexes in Organic Synthesis. Part 36. Cyclization of Tricarbonyliron Complexes by Oxygen to 4a,9a-Dihydro-9H-carbazoles: Application to the Synthesis of Mukonine, Mukonidine, and Pyrido(3,2,1- jk)carbazoles.

✍ H.-J. KNOELKER; M. WOLPERT 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Transition-Metal Complexes in Organic Synthesis. Part 36. Cyclization of Tricarbonyliron Complexes by Oxygen to 4a,9a-Dihydro-9Hcarbazoles: Application to the Synthesis of Mukonine, Mukonidine, and Pyrido(3,2,1-jk)carbazoles. -A novel method for the cyclization of aryl-substituted iron complexes su

Palladium Complexes of 1,3,5,7-Tetrameth

Palladium Complexes of 1,3,5,7-Tetramethyl-2,4,8-trioxa-6-phenyl-6-phosphaadamantane: Synthesis, Crystal Structure and Use in the Suzuki and Sonogashira Reactions and the α-Arylation of Ketones.

✍ George Adjabeng; Tim Brenstrum; Christopher S. Frampton; Al J. Robertson; John H 📂 Article 📅 2004 🏛 John Wiley and Sons ⚖ 42 KB 👁 1 views