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Electron-poor 2,3-Dihydro-1,3-Diborolyl Complexes of Iron and Ruthenium: Synthesis, Reactivity, and Crystal and Electronic Structures of an Iron Sandwich Complex

✍ Scribed by Dr. Ralph Hettrich; Dipl.-Chem. Michael Kaschke; PD Dr. Hubert Wadepohl; Dr. Wolfgang Weinmann; Dr. Martin Stephan; Dr. Hans Pritzkow; Prof. Dr. Walter Siebert; Dr. Isabella Hyla-Kryspin; Prof. Dr. Rolf Gleiter


Publisher
John Wiley and Sons
Year
1996
Tongue
English
Weight
930 KB
Volume
2
Category
Article
ISSN
0947-6539

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Electron-Poor 2,3-Dihydro-1,3-diborolyl
✍ Thomas Müller; Michael Kaschke; Melanie Strauch; Achim Ginsberg; Hans Pritzkow; 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 418 KB

The addition products of lithium alkyls and the pentaalkyl-analyses. At low temperature the interaction of 2\*a, c, or e with H 2 yields the classic dihydride complexes 7\*a, c, and e, 2,3-dihydro-1,3-diborole derivatives 5a-f react with [{(C 5 Me 5 )RuCl} 4 ] and [{(C 5 Me 4 Et)RuCl} 4 ] to form th