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Synthesis, structure, and13C and31P CP/MAS NMR of the tetraphenylantimony(V) di-iso-propyl phosphorodithioate complex [Sb(C6H5)4{S2P(O-iso-C3H7)2}] and its solvated form [Sb(C6H5)4{S2P(O-iso-C3H7)2}] · 1/2C6H6: An example of the monodentate coordination of dithio ligands

✍ Scribed by M. A. Ivanov; V. V. Sharutin; A. V. Ivanov; A. V. Gerasimenko; O. N. Antzutkin


Book ID
110182267
Publisher
SP MAIK Nauka/Interperiodica
Year
2009
Tongue
English
Weight
348 KB
Volume
54
Category
Article
ISSN
0036-0236

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Reaction of elemental antimony with sulfur under mild hydrothermal conditions yielded different polysulfidoclusters of antimony. These were isolated as tetraphenylphosphonium salts [P(C 6 H 5 ) 4 ] 3 Sb 3 S 25 and [P(C 6 H 5 ) 4 ] 2 Sb 2 S 15 2(C 3 N 2 H 6 ) and their crystal structures were determi