Synthesis, structure and the e.s.r. spectrum of the mixed-valence molybdovandate Na2(NH4)4[(VIVVV8Mo)O28] · 10H2O
✍ Scribed by Chuanjiang Hu; Chunying Duan; Qingjin Meng; Yongjiang Liu; Changsheng Lu; Xiaoming Reng; Yijun Chen; Mi Cao
- Book ID
- 110246765
- Publisher
- Springer
- Year
- 2000
- Tongue
- English
- Weight
- 101 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0340-4285
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📜 SIMILAR VOLUMES
The preparation of complex 1 . ~~4 and its crystal structure analysis have both been reported [S.Xl. The synthesis of the N-methylated nickel chelates roc-5.6 will be reported at a later date. In contrast to ruc-4[8], rw-5,6 are 1101 oxygen-sensitive. ## Cation Inclusion within the Mixed-Valence
The title compound (named MU-~) is a new layered aluminophosphate with a unusual Al/P ratio for this kind of materials. Mu-4 was obtained From a quasi nonaqueous mixture involving mainly diethylfonnamide (DEF) as solvent, in addition to limited amounts of water. DEF is decomposed during the synthesi