Synthesis, Structure, and Redox Behavior of the Dehydroannulenes Fused with Bicyclo[2.2.2]octene Frameworks
โ Scribed by Nishinaga, Tohru; Kawamura, Tetsu; Komatsu, Koichi
- Book ID
- 126042452
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 281 KB
- Volume
- 62
- Category
- Article
- ISSN
- 0022-3263
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๐ SIMILAR VOLUMES
Novel naphthalene derivative 4 annelated with four bicyclo[2.2.2]octene frameworks was synthesized. X-ray analysis showed that the acene core of 4 deviates from planarity. The remarkable effect of annelation was observed in its oxidizability as revealed by cyclic voltammetry, and 4 was readily conve
The COT derivative 3 having rigid a-frameworks has been newly synthesized and its X-ray Structure determined; 3 is readily reduced to the aXanion J2. in spite of severe steric hindrance.
Anthracene derivative 4 annelated with four bieycio[2.2.2]octeae (BCO) units was newly synthesized by the Diels--Alder reaction of BCO dimer withp-benzoquinone as a key reaction, and its electronic properties w~'e investigated. The remarkable effect of BCO annelation wasobserved in its redox belmvio