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Synthesis, structure and properties of naphthalene fully annelated with bicyclo[2.2.2]octene frameworks

โœ Scribed by Akira Matsuura; Tohru Nishinaga; Koichi Komatsu

Publisher
Elsevier Science
Year
1999
Tongue
French
Weight
230 KB
Volume
40
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Novel naphthalene derivative 4 annelated with four bicyclo[2.2.2]octene frameworks was synthesized. X-ray analysis showed that the acene core of 4 deviates from planarity. The remarkable effect of annelation was observed in its oxidizability as revealed by cyclic voltammetry, and 4 was readily convetted to highly stable radical cation 4 +. and to the dieation 42+ .

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