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Synthesis and electronic properties of anthracene fully annelated with bicyclo[2.2.2]octene frameworks

โœ Scribed by Akira Matsuura; Tohru Nishinaga; Koichi Komatsu

Publisher
Elsevier Science
Year
1997
Tongue
French
Weight
213 KB
Volume
38
Category
Article
ISSN
0040-4039

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โœฆ Synopsis

Anthracene derivative 4 annelated with four bieycio[2.2.2]octeae (BCO) units was newly synthesized by the Diels--Alder reaction of BCO dimer withp-benzoquinone as a key reaction, and its electronic properties w~'e investigated. The remarkable effect of BCO annelation wasobserved in its redox belmvior, and 4 was readily transformed into stable cation radical 4 +" and dication 42 +.

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