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Synthesis, structure, and reactions of the first homoleptic lithium-arsenic compound, [Li(μ-AsR2)]3 (R = CH(SiMe3)2)

✍ Scribed by Peter B. Hitchcock; Michael F. Lappert; Stephen J. Smith


Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
249 KB
Volume
320
Category
Article
ISSN
0022-328X

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✍ Karl Wilhelm Klinkhammer 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 153 KB 👁 2 views

The two hypersilylcuprates LiCu 2 Hyp 3 (2) and [Li 7 (O t Bu) 6 ][Cu 2 Hyp 3 ] (3) (Hyp = Si(SiMe 3 ) 3 ) were synthesized by reactions of unsolvated lithium hypersilanide, Li-Hyp with hypersilylcopper and CuO t Bu, respectively. Both contain the novel A-frame trihypersilyldicuprate anion [Cu 2- Hy