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The Reaction of Diazomethane Derivatives with the Dielement Compounds R2Al–AlR2 and R2Ga–GaR2 [R = CH(SiMe3)2] – Insertion versus Fragmentation

✍ Scribed by Werner Uhl; Frank Hannemann


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
166 KB
Volume
1999
Category
Article
ISSN
1434-1948

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A Methylene-Bridged Dialuminium Compound
✍ Werner Uhl; Frank Hannemann; Wolfgang Saak; Rudolf Wartchow 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 304 KB

Sodium nitrite (NaNO 2 ) dissolves readily in THF, when the aluminium atom to form a five-membered Al 2 CNO heterocycle. The second oxygen atom of the nitrite anion is not methylene-bridged dialuminium compound R 2 Al-CH 2 -AlR 2 [R = CH(SiMe 3 ) 2 ] 1 with two coordinatively unsaturated affected. S