Formation of the Digallium Compound [(C5C6)2N3](R)Ga–Ga(R)[N3(C6H5)2] with Two Bis(trimethylsilyl)methyl Groups and Two Terminal Chelating Diphenyltriazenido Ligands

Oxidative Addition Reactions of Organorh

Oxidative Addition Reactions of Organorhodium(I) Complexes Containing the Tridentate Ligand 2,6-Bis(diphenylphosphanylmethyl)pyridine [Rh(PNP)R] (R = CH3, C6H5) with Iodine and Methyl Iodide and Investigation of the Reductive Elimination

✍ Christine Hahn; Michael Spiegler; Eberhardt Herdtweck; Rudolf Taube 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 261 KB 👁 2 views

As part of studies aimed at delineating the mechanism of the rhodium(III) complexes 2a,b and 3a,b have been characterized by 31 P-, 1 H-, and 13 C-NMR spectrometry, as rhodium complex-catalyzed hydroamination of olefins, the model complexes [Rh(PNP)R] (R = CH 3 1a, C 6 H 5 1b) have well as by EI mas