Bis(trimethylsilyl)phosphidometal complexes: I. Isolation and NMR spectra of Li4(μ2-PR2)2(μ3-PR2)2(THF)2 (I), Li(PR2(PMDETA) (II), and X-ray structures of compound I and [Li(μ-PR2)(THF)2]2 (III) (R = SiMe3)
✍ Scribed by Evamarie Hey; Peter B. Hitchcock; Michael F. Lappert; Audesh K. Rai
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 740 KB
- Volume
- 325
- Category
- Article
- ISSN
- 0022-328X
No coin nor oath required. For personal study only.
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Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged
## Dedicated to Prof. Huns-Georg uon Schnering on the occasion of his 60th birthday (1 7.V. 9 I) The cluster compounds [Pt,(,u-CO),(PR,),] act as Lewis bases towards the metal halides of Group XI, MX, Group XII, MX,, and Group XIII, MX,, to form cluster compounds of the composition [{MX,}{Pt3(,u-