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Synthesis, structure and properties of the cluster anions [(Mo6Cl8i)X6a]2− with XaF, Cl, Br, I

✍ Scribed by Preetz, Wilhelm; Harder, Karsten; von Schnering, H.G.; Kliche, Gerhard; Peters, Karl


Book ID
123452923
Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
758 KB
Volume
183
Category
Article
ISSN
0925-8388

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Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] ´n EtOH ´m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 ´6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The