✦ LIBER ✦
Compounds with Cluster Cations together with Cluster Anions [(M6X12)(EtOH)6]2+ besides [(Mo6Cl8)Cl4X2]2– (M = Nb, Ta; X = Cl, Br) – Synthesis and Crystal Structures
✍ Scribed by I. Bašic; N. Brničević; U. Beck; A. Simon; R. E. McCarley
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- German
- Weight
- 179 KB
- Volume
- 624
- Category
- Article
- ISSN
- 0372-7874
No coin nor oath required. For personal study only.
✦ Synopsis
Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] ´n EtOH ´m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 ´6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The structures of [(Nb 6 Cl 12 )(