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Synthesis, structural characterization and electronic structures of the [Fe6S6(X)6(Mo(CO)3)2]3- clusters (X = Cl, Br)

✍ Scribed by Coucouvanis, D.; Salifoglou, A.; Kanatzidis, M. G.; Simopoulos, A.; Kostikas, A.


Book ID
121872065
Publisher
American Chemical Society
Year
1987
Tongue
English
Weight
914 KB
Volume
109
Category
Article
ISSN
0002-7863

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Compounds with Cluster Cations together
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Compounds consisting of both cluster cations and cluster anions of the composition [(M 6 X 12 )(EtOH) 6 ][(Mo 6 Cl 8 )Cl 4 X 2 ] Β΄n EtOH Β΄m Et 2 O (M = Nb, Ta; X = Cl, Br) have been prepared by the reaction of (M 6 X 12 )X 2 Β΄6 EtOH with (Mo 6 Cl 8 )Cl 4 . IR data are given for three compounds. The