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Synthesis, Structure, and Physical Properties of Mixed Valent Mo 2 SbS 2 , the First Superconducting Antimonide-Sulfide

✍ Scribed by Lee, Chi-Shen; Safa-Sefat, A.; Greedan, J. E.; Kleinke, Holger


Book ID
125931814
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
192 KB
Volume
15
Category
Article
ISSN
0897-4756

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Synthesis, Structure, and Thermoelectric
✍ Chi-Shen Lee; Holger Kleinke πŸ“‚ Article πŸ“… 2002 πŸ› John Wiley and Sons 🌐 English βš– 367 KB πŸ‘ 2 views

The structure of a new ternary compound, MoSb 2 S, was identified by single-crystal X-ray diffraction. The title compound was synthesized by heating the elements in stoichiometric ratios in sealed silica tubes at 600-800 Β°C using small amounts of I 2 as a mineralizator. The compound crystallizes in