Synthesis, Structure, and Thermoelectric Properties of the New Antimonide Sulfide MoSb2S

✍ Scribed by Chi-Shen Lee; Holger Kleinke

• Publisher: John Wiley and Sons
• Year: 2002
• Tongue: English
• Weight: 367 KB
• Volume: 2002
• Category: Article
• ISSN: 1434-1948
• DOI: 10.1002/1099-0682(200203)2002:3<591::aid-ejic591>3.0.co;2-r

✦ Synopsis

The structure of a new ternary compound, MoSb 2 S, was identified by single-crystal X-ray diffraction. The title compound was synthesized by heating the elements in stoichiometric ratios in sealed silica tubes at 600-800 °C using small amounts of I 2 as a mineralizator. The compound crystallizes in a new structure type in the monoclinic space group C2/m [a = 36.157