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Dimorphism of K4Ta2S11: Syntheses, Crystal Structures, and Properties of two Alkali Metal Tantalum Sulfides

✍ Scribed by Sabine Herzog; Christian Näther; Wolfgang Bensch


Publisher
John Wiley and Sons
Year
1999
Tongue
German
Weight
152 KB
Volume
625
Category
Article
ISSN
0372-7874

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Synthesis and Crystal Structure of a New
✍ Sabine Herzog; Christian Näther; Peter Dürichen; Wolfgang Bensch 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 93 KB 👁 1 views

Needle-shaped, moisture sensitive, yellow crystals of Na 3 TaS 4 were obtained by the reaction of Na 2 S 3 , Ta, and S at 450 °C. The structure was determined by single crystal X-ray diffraction and refined to R1 and wR2 values of 0.0172 and 0.0381, respectively. Na 3 TaS 4 crystallizes with 32 form