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Syntheses, Crystal Structures, and Properties of the Novel Thioborates KBa4(BS3)3 and K4Ba11(BS3)8S

✍ Scribed by A. Hammerschmidt; C. Jansen; J. Küper; C. Köster; B. Krebs


Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
189 KB
Volume
627
Category
Article
ISSN
0372-7874

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Systematic studies on quaternary thio-and selenoborates containing heavier alkaline earth metal cations led to the two new isotypic crystalline phases Sr 4.2 Ba 2.8 (BS 3 ) 4 S and Ba 7 (BSe 3 ) 4 Se. Both compounds consist of trigonal-planar BQ 3 (Q = S, Se) units, isolated Q 2± anions and the corr