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Syntheses, Crystal Structures, and Properties of New Ternary Chalcogenides of Group 4 Metals: Rb4Ti3S14, Cs4Zr3S14, K4Hf3Se14, and K4ZrHf2Se14

✍ Scribed by Ralf Tillinski; Christian Rumpf; Wolfgang Bensch


Publisher
John Wiley and Sons
Year
2001
Tongue
German
Weight
128 KB
Volume
627
Category
Article
ISSN
0372-7874

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✍ Sandra Löken; Wolfgang Tremel 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 180 KB 👁 2 views

The new compounds K 2 Au 2 Ge 2 S 6 (1), K 2 Au 2 Sn 2 Se 6 (2), and Cs 2 Au 2 SnS 4 (3) have been synthesized through direct reaction of the elements with a molten polyalkalithiogermanate(stannate) flux at 650, 550, and 400 °C, respectively. Their crystal structures have been determined by single c