✦ LIBER ✦

Synthesis, structure and non-linear optical property of a copper(II) thiocyanate three-dimensional supramolecular compound

✍ Scribed by Hai-Ying Bie; Jie-Hui Yu; Ji-Qing Xu; Jing Lu; Yong Li; Xiao-Bing Cui; Xiao Zhang; Ying-Hua Sun; Ling-Yun Pan

Publisher: Elsevier Science
Year: 2003
Tongue: English
Weight: 177 KB
Volume: 660
Category: Article
ISSN: 0022-2860
DOI: 10.1016/j.molstruc.2003.08.011

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✦ Synopsis

A novel copper(II) thiocyanate complex [Cu(im) 2 (NCS) 2 ] 1 (im ¼ imidazole) has been prepared and characterized by spectroscopic analysis and crystallographic method. This supramolecular compound exhibits a three-dimensional solid state structure constituted by N-H• • •S hydrogen bonds and p-p stacking interactions. The compound in DMF solutions has a very strong third-order non-linear optical (NLO) behavior with absorption coefficient and refractive index a 2 ¼ 1:18 £ 10 211 m Â w 21 ; n 2 ¼ 29:00 £ 10 216 m 2 w 21 ; respectively, and third-order NLO susceptibility x ð3Þ of 7.00 £ 10 210 esu.

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