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Synthesis, crystal structure and third-order non-linear optical property of heterobimetallic cluster compound [MoOICu3S3(2,2′-bipy)2]

✍ Scribed by Yong Li; Jing Lu; Jiqing Xu; Xiaobing Cui; Yinghua Sun; Qingxin Yang; Lingyun Pan


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
154 KB
Volume
690
Category
Article
ISSN
0022-2860

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## Abstract Nest‐shaped cluster [CuBr(bpy)~2~][MoOS~3~Cu3Br~2~(bpy)] was synthesized by the treatment of (NH~4~)~2~ MOO~2~S~2~, CuBr and Et~4~NBr with bpy (2,2′‐bipyridyl) in CH~3~CN. Its structure has been characterized by X‐ray diffraction; monoclinic, space group __P__2~1~/__n__ ‐ with __a__ = l