Synthesis, crystal structure and third-order nonlinear optical properties of a hexanuclear cluster [WOS3Cu2(4-tBuPy)2]2 (4-tBuPy = 4-tert-butylpyridine)
โ Scribed by Bing Wu; Wen-Hua Zhang; Hong-Xi Li; Zhi-Gang Ren; Jian-Ping Lang; Yong Zhang; Ying-Lin Song
- Publisher
- Elsevier Science
- Year
- 2007
- Tongue
- English
- Weight
- 207 KB
- Volume
- 829
- Category
- Article
- ISSN
- 0022-2860
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A novel three-dimensional hybrid solid, [{(Cu 4 I 4 ) 2 H 2 O}{Cu 6 (mtz) 6 }] n (1) (Hmtz = 3,5-dimethyl-1,2,4-triazole), was synthesized under solvothermal condition. The structure of 1 consists of four-connected Cu 4 I 4 clusters and hexanuclear Cu 6 (mtz) 6 rings as secondary building units (SBU
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