Synthesis, crystal structure and third-order nonlinear optical properties of heterometallic cluster [WM2S4(Pph3)3]·DMF (M2=1.25Ag+0.75Cu)
✍ Scribed by Zhao-Xia Zhang; Yong Li; Ke-Chang Li; Wen-Dong Song; Qiu-Shun Li; Hao-Ping Xiong; Ji-Qing Xu; Ling-Yun Pan
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 145 KB
- Volume
- 791
- Category
- Article
- ISSN
- 0022-2860
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## Abstract Nest‐shaped cluster [CuBr(bpy)~2~][MoOS~3~Cu3Br~2~(bpy)] was synthesized by the treatment of (NH~4~)~2~ MOO~2~S~2~, CuBr and Et~4~NBr with bpy (2,2′‐bipyridyl) in CH~3~CN. Its structure has been characterized by X‐ray diffraction; monoclinic, space group __P__2~1~/__n__ ‐ with __a__ = l
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
A novel bis (dmit) complex of copper (II), [(C 3 H 7 ) 4 N] 2 [Cu(dmit) 2 ] (1), where dmit is 2-thioxo-1,3-dithiole-4,5-dithiolate, was prepared and structurally characterized by X-ray single crystal diffraction. The copper (II) atom is tetracoordinated by four dmit S atoms, forming a nearly square