Hydrothermal Syntheses, Supramolecular Structures and the Third-order Non-linear Optical Properties of Three Copper (I) Halide Amine Complexes Connected via Secondary Bonding Interactions
✍ Scribed by Jie-Hui Yu; Ji-Qing Xu; Li Han; Tie-Gang Wang; Zhan Shi; Wei-Jie Jing; Hong Ding; Jia-Ning Xu; Hong-Bin Jia; Jia Hua
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 455 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0256-7660
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✦ Synopsis
The hydrothermal reactim of cul, KI and bidentate amineS [l,lO-phenanthrdiW (phen) or ethylenediamine (en)] gave thethree copper(1) halide compouods, CIbI,(phen), (11, ~( p h e n ) , ( t ) and [ W e n ) , l [ ~z 1 2 ( 3 ) , which were structurally characterized via singlecrystal X-ray diffraction studies. Hydrogen bonds and z-n interactim are the most remarkable stn~ctwal featma of the title mmpounds. An be denected via t h e secondary bonding. Moreover, the title compounds were characterized by elemental analyses, I R spectra and TGA analyses. 'Ihe third-order non-linear optid properties of the title compounds were also investigated and all exhilit nicer noo-linear absorption and self-focuohg perfonnan~e. Keywords order non-linear optical property, supramolecular structure m i BE higher-dimensid supramolecular compounds concopper( I) halide, hydrothermal synthesis, the third-' Recently much attention has been paid to the hydrogen bonds and x-x interactions in the area of metal-ligand