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Synthesis, structure and hydrosilylation activity of neutral and cationic rare-earth metal silanolate complexes

✍ Scribed by Elvidge, Benjamin R. ;Arndt, Stefan ;Spaniol, Thomas P. ;Okuda, Jun


Book ID
120031371
Publisher
Royal Society of Chemistry
Year
2006
Tongue
English
Weight
421 KB
Volume
7
Category
Article
ISSN
1477-9226

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Synthesis and Structural Characterizatio
✍ Hans W. GΓΆrlitzer; Michael Spiegler; Reiner Anwander πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 316 KB πŸ‘ 3 views

The reaction of rare earth silylamides Ln[N(SiHMe 2 ) 2 ] 3 (thf) n performed on the solvent-free, dinuclear yttrium derivative 5 revealed an unusual Β΅ 2 ,Ξ· 4 :Ξ· 1 -coordination of the [n = 1 for Sc (1a); n = 2 for Y (1b), La (1c), Nd (1d)] with trans-1,2-bis(2,4,6-triisopropylbenzenesulfonamido)cyc