𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Neutral and Monocationic Half-Sandwich Methyl Rare-Earth Metal Complexes: Synthesis, Structure, and 1,3-Butadiene Polymerization Catalysis

✍ Scribed by Dominique Robert; Thomas P. Spaniol; Jun Okuda

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
422 KB
Volume
2008
Category
Article
ISSN
1434-1948

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Cationic Allyl Complexes of the Rare-Ear
Cationic Allyl Complexes of the Rare-Earth Metals: Synthesis, Structural Characterization, and 1,3-Butadiene Polymerization Catalysis
✍ Dominique Robert; Elise Abinet; Thomas P. Spaniol; Jun Okuda 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 387 KB 👁 3 views

## Abstract Monocationic bis‐allyl complexes [Ln(η^3^‐C~3~H~5~)~2~(thf)~3~]^+^[B(C~6~X~5~)~4~]^−^ (Ln=Y, La, Nd; X=H, F) and dicationic mono‐allyl complexes of yttrium and the early lanthanides [Ln(η^3^‐C~3~H~5~)(thf)~6~]^2+^[BPh~4~]~2~^−^ (Ln=La, Nd) were prepared by protonolysis of the tris‐allyl

Synthesis and Structure of Trisilane-1,3
Synthesis and Structure of Trisilane-1,3-diyl ansa Half-Sandwich Complexes of Group 6 Metals
✍ Holger Braunschweig; Rainer Dörfler; Kai Hammond; Jan Mies; Krzysztof Radacki 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 156 KB 👁 1 views

## Abstract We present the synthesis and characterization of the firsttrisila‐bridged __ansa__ half‐sandwich complexes of Group 6 transition metals in a one‐step synthesis from dilithiatedprecursors Li[M(η^5^‐C~5~H~4~Li)(CO)~3~] (M = W, Mo) by use ofstoichiometric amounts of Si~3~Me~6~Cl~2~ under d