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Half-Sandwich Bis(tetramethylaluminate) Complexes of the Rare-Earth Metals: Synthesis, Structural Chemistry, and Performance in Isoprene Polymerization

✍ Scribed by Melanie Zimmermann; Karl W. Törnroos; Helmut Sitzmann; Reiner Anwander

Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
617 KB
Volume
14
Category
Article
ISSN
0947-6539

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✍ Dominique Robert; Elise Abinet; Thomas P. Spaniol; Jun Okuda 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 387 KB 👁 3 views

## Abstract Monocationic bis‐allyl complexes [Ln(η^3^‐C~3~H~5~)~2~(thf)~3~]^+^[B(C~6~X~5~)~4~]^−^ (Ln=Y, La, Nd; X=H, F) and dicationic mono‐allyl complexes of yttrium and the early lanthanides [Ln(η^3^‐C~3~H~5~)(thf)~6~]^2+^[BPh~4~]~2~^−^ (Ln=La, Nd) were prepared by protonolysis of the tris‐allyl