Synthesis, structure, and catalytic activity of palladium complexes with new chiral cyclohexane-1,2-based di-NHC-ligands
β Scribed by Gongwo Shigeng; Junkai Tang; Dao Zhang; Quanrui Wang; Zhenxia Chen; Linhong Weng
- Book ID
- 116680287
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 964 KB
- Volume
- 700
- Category
- Article
- ISSN
- 0022-328X
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π SIMILAR VOLUMES
The reaction of 1,2-diamines la-c with Ph3PBr2 in the presence of triethylamine gives rise to the corresponding diphosphonium salts 2a-c in good yields. Treatment of these salts with NaH at room temperature in CH,Cl, affords the diiminophosphoranes 3a-c in near quantitative yields. Derivatives 3a,b
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