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Synthesis, spectroscopic and structural characterization of cobalt(II) complex with uracil-containing 2,6-diformylpyridine ligand: Theoretical studies on the ligand and pentagonal-bipyramidal [Co(L)(H2O)2]2+ and [Zn(L)(H2O)2]2+ cations

✍ Scribed by Gamze Koz; Namık Özdemir; Demet Astley; Muharrem Dinçer; Stephen T. Astley


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
480 KB
Volume
966
Category
Article
ISSN
0022-2860

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Dinuclear Manganese and Cobalt Complexes
✍ Shinnosuke Inami; Masaki Nishio; Yoshihito Hayashi; Kiyoshi Isobe; Hiroyuki Kame 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 492 KB

## Abstract An all‐inorganic complex, [Mn~2~{(VO~3~)~5~}~2~]^6–^ (1), was synthesized, and the structure determination reveals a dinuclear manganese complex coordinated by two cyclic pentavanadate ligands. The cyclic pentavanadate units sandwich the edge‐sharing octahedral dimanganese core through