Dinuclear Manganese and Cobalt Complexes
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Shinnosuke Inami; Masaki Nishio; Yoshihito Hayashi; Kiyoshi Isobe; Hiroyuki Kame
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Article
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2009
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John Wiley and Sons
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English
⚖ 492 KB
## Abstract An all‐inorganic complex, [Mn~2~{(VO~3~)~5~}~2~]^6–^ (1), was synthesized, and the structure determination reveals a dinuclear manganese complex coordinated by two cyclic pentavanadate ligands. The cyclic pentavanadate units sandwich the edge‐sharing octahedral dimanganese core through