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Synthesis, characterization and crystal structures of two discrete Cu(II) complexes with mixed-ligands: [Cu(mal)(L)(H2O)]·H2O and [Cu(Phmal)(L)2] (mal=malonate dianion, phmal=phenylmalonate dianion and L=5,5′-dimethyl-2,2′-bipyridine)

✍ Scribed by Guang-Hua Cui; Jian-Rong Li; Tong-Liang Hu; Xian-He Bu


Publisher
Elsevier Science
Year
2005
Tongue
English
Weight
164 KB
Volume
738
Category
Article
ISSN
0022-2860

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✍ Xian Peng; Guang-Hua Cui; De-Jie Li; Shang-Zhuo Wu; Ya-Mei Yu 📂 Article 📅 2010 🏛 Elsevier Science 🌐 English ⚖ 581 KB

A mononuclear copper(II) complex, [Cu(mal)(PIM) 2 (H 2 O)] (1) [mal = malonate dianion, PIM = 2-propylimidazole] has been synthesized and characterized by elemental analysis, IR, UV-Vis, TG-DTA, and single crystal X-ray diffraction. The center Cu(II) atom in the complex has a distorted square-pyrami