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ChemInform Abstract: Dinuclear Manganese and Cobalt Complexes with Cyclic Polyoxovanadate Ligands: Synthesis and Characterization of [Mn2V10O30]6- and [Co2(H2O)2V10O30] 6-.

✍ Scribed by Shinnosuke Inami; Masaki Nishio; Yoshihito Hayashi; Kiyoshi Isobe; Hiroyuki Kameda; Tatsuya Shimoda

Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
41
Category
Article
ISSN
0931-7597

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πŸ“œ SIMILAR VOLUMES

Dinuclear Manganese and Cobalt Complexes
Dinuclear Manganese and Cobalt Complexes with Cyclic Polyoxovanadate Ligands: Synthesis and Characterization of [Mn2V10O30]6– and [Co2(H2O)2V10O30]6–
✍ Shinnosuke Inami; Masaki Nishio; Yoshihito Hayashi; Kiyoshi Isobe; Hiroyuki Kame πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 492 KB

## Abstract An all‐inorganic complex, [Mn~2~{(VO~3~)~5~}~2~]^6–^ (1), was synthesized, and the structure determination reveals a dinuclear manganese complex coordinated by two cyclic pentavanadate ligands. The cyclic pentavanadate units sandwich the edge‐sharing octahedral dimanganese core through

Synthesis and Crystal Structure of a Nov
Synthesis and Crystal Structure of a Novel Dinuclear Copper(II) Complex, [Cu2(phen)2(H2O)2(OH)2](HCO3)2 Β· 6 H2O with phen = 1,10-phenanthroline
✍ Yue-Qing Zheng; Jie Sun; Jian-Li Lin πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 German βš– 91 KB πŸ‘ 2 views

Dark blue plate-like crystals of [Cu 2 (phen) 2 (H 2 O) 2 (OH) 2 ](HCO 3 ) 2 ´6 H 2 O were obtained from a CH 3 OH±H 2 O solution containing CuCl 2 , 1,10-phenanthroline (phen), sebacic acid and Na 2 CO 3 . The crystal structure (triclinic, P 1 (no. 2), a = 8.118(1), b = 9.624(1), c = 10.536(1) A Ê