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Synthesis of β-d-fructofuranosyl-(2→1)-2-acetamido-2-deoxy-α-d-glucopyranoside (N-acetylsucrosamine) using β-fructofuranosidase-containing Aspergillus oryzae mycelia as a whole-cell catalyst

✍ Scribed by Takako Hirano; Toru Wada; Sumire Iwai; Hitoshi Sato; Makoto Noda; Mai Juami; Masatoshi Nakamura; Yasuko Kumaki; Wataru Hakamata; Toshiyuki Nishio


Book ID
119215037
Publisher
Elsevier Science
Year
2012
Tongue
English
Weight
892 KB
Volume
353
Category
Article
ISSN
0008-6215

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Treatment of benzyl O-/?-n-galactopyranosyl-( 1+3)-2-acetamido-2-deoxy-4,6-O-isopropylidene-j3-D-glucopyranoside with tert-butylchlorodiphenylsiiane afforded the 6'-0-tert-butyldiphenylsilyl ether, which was converted into the 3',4'-0-isopropylidene derivative. Methylation and subsequent removal of