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Synthesis of β-Alkyl-α-bromoacrylic Ethyl Esters 1

✍ Scribed by Stacy, Gardner W.; Wagner, George D.

Book ID
126226820
Publisher
American Chemical Society
Year
1952
Tongue
English
Weight
409 KB
Volume
74
Category
Article
ISSN
0002-7863

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Facile synthesis of β-alkyl-substituted
Facile synthesis of β-alkyl-substituted esters from α,β-unsaturated aldehydes
✍ Tsujiaki Hata; Masashi Nakajima; Mitsuo Sekine 📂 Article 📅 1979 🏛 Elsevier Science 🌐 French ⚖ 210 KB

8-Alkyl-substituted carboxylates were synthesized in good yields from U,B-unsaturated aldehydes by using the 1:l carbonyl adducts with diethyl bis(trimethylsily1) phosphite. Recently, several studies on acyl anion equivalents utilizing carbonyl insertion reactions have appeared. 2 It has been report