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Synthesis of α-Substituted 3-Ulosonic Acids from Aldonolactones.

✍ Scribed by Rene Csuk; Ulrike Franke; Zhong Hu; Claus Krieger

Publisher
John Wiley and Sons
Year
2004
Weight
139 KB
Volume
35
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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A Thermostable Aldolase for the Synthesis of 3-Deoxy-2-ulosonic Acids
✍ Henry J. Lamble; Sylvain F. Royer; David W. Hough; Michael J. Danson; Garry L. T 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 87 KB 👁 2 views

## Abstract A stereochemically promiscuous 2‐keto‐3‐deoxygluconate aldolase has been used as an efficient biocatalyst to catalyse the aldol reaction of pyruvate with C~3~‐ and C~4~‐aldoses to afford __syn__‐ and __anti__‐3‐deoxy‐2‐ulosonic acids in poor to good __de__. A continuous flow bioreactor