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Synthesis and Use of α-Silyl-Substituted α-Hydroxyacetic Acids.

✍ Scribed by Carsten Bolm; Andrey Kasyan; Peter Heider; Sandra Saladin; Karlheinz Drauz; Kurt Guenther; Christoph Wagner

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
33
Category
Article
ISSN
0931-7597

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Synthesis of α-Substituted α-Aminophosphinic and α-Aminophosphonic Acids. -The reaction of ketoximes (I) with hypophosphorous acid affords previously unknown phosphinic acids (II), which are smoothly oxidized into the corresponding phosphonic acids (III). -(OSIPOVA, T. I.;