Synthesis of α-Glycosyl Thiols by Stereospecific Ring-Opening of 1,6-Anhydrosugars
✍ Scribed by Zhu, Xiangming; Dere, Ravindra T.; Jiang, Junyan; Zhang, Lei; Wang, Xiaoxia
- Book ID
- 118748071
- Publisher
- American Chemical Society
- Year
- 2011
- Tongue
- English
- Weight
- 477 KB
- Volume
- 76
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
Ab.rtraet:Ring-openingof an u-1,2-cpoxidefunctionin sugars with lithium afkynylderivativesin the presenceof zinc chforidepmeecdswith retentionof configurationto afford a-C-(alkynyl)-glycosidesin reasonableyields. @ 1997Elsevier ScienceLtd.
Stereoselective Synthesis of α-C-(Alkynyl)-glycosides via Ring-Opening of α-1,2-Anhydrosugars. -In the presence of ZnCl2 the α-1,2-epoxide function in sugars is selectively ring-opened by lithium alkynyl derivatives to form α -glycosides with retention of configuration. -