Stereoselective Synthesis of α-C-(Alkynyl)-glycosides via Ring-Opening of α-1,2-Anhydrosugars. -In the presence of ZnCl2 the α-1,2-epoxide function in sugars is selectively ring-opened by lithium alkynyl derivatives to form α -glycosides with retention of configuration. -
✦ LIBER ✦
Stereoselective Synthesis of α-C-(alkynyl)-glycosides via Ring-opening of α-1,2-Anhydrosugars
✍ Scribed by Michiel A Leeuwenburgh; Cornelis M Timmers; Gijsbert A van der Marel; Jacques H van Boom; Jean-Maurice Mallet; Pierre G Sinaÿ
- Book ID
- 104257731
- Publisher
- Elsevier Science
- Year
- 1997
- Tongue
- French
- Weight
- 456 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0040-4039
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✦ Synopsis
Ab.rtraet:Ring-openingof an u-1,2-cpoxidefunctionin sugars with lithium afkynylderivativesin the presenceof zinc chforidepmeecdswith retentionof configurationto afford a-C-(alkynyl)-glycosidesin reasonableyields. @ 1997Elsevier ScienceLtd.
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract, please click on HTML or PDF.
From α-1,2-Anhydrosugars to C-Glycosides
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