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A direct and stereospecific approach to the synthesis of α-glycosyl thiols

✍ Scribed by Dere, Ravindra T.; Wang, Yingxi; Zhu, Xiangming


Book ID
120325381
Publisher
Royal Society of Chemistry
Year
2008
Tongue
English
Weight
108 KB
Volume
6
Category
Article
ISSN
1477-0520

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The synthesis of the C-glycoside analogue of the disaccharide Man-(a1 32)Man has been achieved in a highly stereoselective and efficient manner employing an approach which closely parallels O-glycoside synthesis. The key step included the samarium diiodide reduction of mannosyl pyridylsulfone 18 in