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Stereospecific approach to the synthesis of quinine and related alkaloids

✍ Scribed by Coffen, D. L.; McEntee, T. E.


Book ID
126901693
Publisher
Royal Society of Chemistry
Year
1971
Weight
155 KB
Volume
11
Category
Article
ISSN
0577-6171

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The synthesis of heliotridine and relate
✍ Jan A. Glinskil; Leon H. Zalkow πŸ“‚ Article πŸ“… 1985 πŸ› Elsevier Science 🌐 French βš– 257 KB

An efficient synthesis of heliotridine from readily available retronecine was accomplished by nucleophilic displacement of the 7-mesylate, in the 7-mesyl-Q-bentoate of retronecine with various cesium carboxylates in DMF, followed by hydrolysis. The synthetic procedure also permits the ready synthesi