𝔖 Bobbio Scriptorium
✦   LIBER   ✦

A new approach to the synthesis of pentacyclic indole derivatives related to Aspidosperma alkaloids

✍ Scribed by Anthony H. Jackson; Patrick V.R. Shannon; David J. Wilkins

Publisher
Elsevier Science
Year
1987
Tongue
French
Weight
186 KB
Volume
28
Category
Article
ISSN
0040-4039

No coin nor oath required. For personal study only.

✦ Synopsis

N-Indolylethyl-Z-pyridones bearing appropriate B-dicarbonyl in the 3iposition have been cyclised to pentacyclic indoles indolenines by catalysis with trifluoroacetic anhydride.

πŸ“œ SIMILAR VOLUMES

A new strategy for the enantioselective
A new strategy for the enantioselective synthesis of aspidosperma alkaloids: II - Achievement of the pentacyclic system.
✍ Didier Desmaele; Jean d'Angelo πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 French βš– 271 KB

## Carbazolone 5 has been converted in eleven steps into alkaloid analog Z (R = Me) (13 46 overall yield). In the preceding paper l, we proposed a new approach to pentacyclic Aspidosperma alkaloids [(e.g. (-)-aspidospermldine, 1, R = Et], based on the disconnection [l -+ 2 -+ 31, in which carbazol

A new approach to the synthesis of lysop
A new approach to the synthesis of lysophosphatidylcholines and related derivatives
✍ Niloufar Bibak; Joseph Hajdu πŸ“‚ Article πŸ“… 2003 πŸ› Elsevier Science 🌐 French βš– 120 KB

A new stereospecific synthesis of lysophosphatidylcholines is reported. The sequence relies on orthogonal protection of hydroxyl groups derived from glyceric acid, using fluorenylmethylcarbonate versus tetrahydropyranyl ether functions, that allow regiospecific introduction of substituents to obtain