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Synthesis of α-Aryl Nitriles through Palladium-Catalyzed Decarboxylative Coupling of Cyanoacetate Salts with Aryl Halides and Triflates

✍ Scribed by Rui Shang; Dong-Sheng Ji; Ling Chu; Prof. Dr. Yao Fu; Prof. Dr. Lei Liu

Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
344 KB
Volume
50
Category
Article
ISSN
0044-8249

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✍ Hyunseok Kim; Phil Ho Lee 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB 👁 2 views

## Abstract Palladium‐catalyzed decarboxylative __sp‐sp__^2^ cross‐coupling reactions of aryl and vinyl halides and triflates with α,β‐ynoic acids using silver oxide have been developed. A variety of α,β‐ynoic acids were readily decarboxylated in the presence of silver oxide and then, generated __i