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Arylation of α-Chiral Ketones by Palladium-Catalyzed Cross-Coupling Reactions of Tosylhydrazones with Aryl Halides

✍ Scribed by Prof. José Barluenga; María Escribano; Prof. Fernando Aznar; Dr. Carlos Valdés

Publisher: John Wiley and Sons
Year: 2010
Tongue: English
Weight: 342 KB
Volume: 49
Category: Article
ISSN: 0044-8249
DOI: 10.1002/anie.201003450

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## Abstract The palladium‐catalyzed cross‐coupling reaction of 1‐aryltriazenes with aryl‐ and alkenyltrifluorosilanes occurs readily at room temperature to yield the corresponding biaryl and stilbene products in moderate to good yields. In contrast to the previous results for the reaction with aren