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Synthesis of α-aminoacids by catalytic palladium (O) alkylation of schiff bases

✍ Scribed by D. Ferroud; J.P. Genet; R. Kiolle


Publisher
Elsevier Science
Year
1986
Tongue
French
Weight
216 KB
Volume
27
Category
Article
ISSN
0040-4039

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Double asymmetric synthesis: Palladium c
✍ J.P. Genet; N. Kopola; S. Juge; J. Ruiz-Montes; O.A.C. Antunes; S. Tanier 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 270 KB

A new double asymmetric induction in carbon-carbon bond formation is -achieved by the use of palladium chiral complexes in the alkylation of chiral Schiff bases1 derived from glycine. High diastereoisomeric excesses are obtained (90-999) using N.N-cyclohexylsulfamoylisobornyl derivatives and DIOP as