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Diastereoselective Alkylation of Schiff Bases for the Synthesis of Lipidic Unnatural Fmoc-Protected α-Amino Acids.

✍ Scribed by Anna Maria Papini; Elena Nardi; Francesca Nuti; Jacques Uziel; Mauro Ginanneschi; Mario Chelli; Alberto Brandi

Publisher: John Wiley and Sons
Year: 2010
Weight: 33 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200252193

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## Abstract The growing interest in the 1,4‐disubstituted‐1,2,3‐triazolyl moiety as an amide bond surrogate and its formation through very mild, chemoselective, and bioorthogonal Cu^I^‐catalyzed Huisgen 1,3‐dipolar [3+2] cycloaddition of an alkynyl to an azido function, presented an unmet need for