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Synthesis of unsymmetrical spin-labelled bolaamphiphiles

✍ Scribed by Mathieu Berchel; Loïc Lemiègre; Jelena Jeftić; Thierry Benvegnu

Book ID: 104095471
Publisher: Elsevier Science
Year: 2008
Tongue: French
Weight: 225 KB
Volume: 49
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2008.05.125

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✦ Synopsis

This work presents the efficient synthesis of a novel spin-labelled bolaamphiphile bearing sugar and cationic polar heads. Preliminary ESR studies were conduced both in CH 2 Cl 2 and water and have confirmed that this methodology can be used to study the transversal rotation (flip-flop) dynamic of membrane involving such bolaamphiphiles.

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